Plasperox TBH - 80's thermal stability provides for safer
handling than other commonly used oxidizing agents. It has a high
self-accelerating decomposition temperature (190°F/88°C). Little to no
decomposition occurs up to moderate temperatures (~100°F/38°C). As a result,
storage and handling do not present the difficulties associated with many
other organic peroxides.
Plasperox TBH - 80 provides versatility and convenience in many applications
because of solvent compatibility. Plasperox TBH - 80's solubility in water is
about 15 wt.%. Plasperox TBH - 80 is also miscible with most organic solvents.
Plasperox TBH - 80 provides excellent reactivity control with appropriate
catalyst choice and often mild reaction conditions. Selectivity advantages
include regioselectivity, stereoselectivity, and chemoselectivity. When
reacted, the byproduct tertiary butyl alcohol is stable. Simple distillation
easily reduces the alcohol to low residual levels.
Plasperox TBH - 80 is also more cost effective than competitive organic
peroxides due to its low price and high efficiency.
HANDLING & STORAGE :
Storage is recommended at less than 200 C. If frozen allow
to thaw at room temperature. Never apply heat. Plasperox TBH - 80 is a yellow
label material. Handle with caution. Keep it away from all sources of Ignition
(Heat, Spark, Flames). Avoid contamination with accelerator and metals. The
biotreatability of aqueous TBHP streams has not been identified. Reducing
agents as well as acids and transition metals ions which may be available in
waste water streams can convert TBHP to tertiary butyl alcohol. No data exists
at this time estimating the percent conversion in a typical waste water
stream. Studies indicate that tertiary butyl alcohol is treatable in
acclimated, well-operated biological treatment systems. However, the
conditions and/or retention time required may exceed typical conditions. The
primary pathways for TBHP removal from soils probably are biodegradation and
transport to groundwater. Available information indicates that Plasperox TBH -
80 should not bioaccumulate in plants and animals.